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Syntheses of carbocyclic aminonucleosides and (−)-epi-4′-carbocyclic puromycin: Application of palladium(0)/indium iodide-allylations and tethered aminohydroxylations
Carbocyclic aminonucleosides and epi-4′-carbocyclic puromycin were prepared from an acylnitroso-derived hetero Diels–Alder cycloadduct. Pd(0)/InI-mediated allylations of a formyl species were used to install the 4′-hydroxymethyl group. A tethered aminohydroxylation strategy was employed to install t...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2903068/ https://ncbi.nlm.nih.gov/pubmed/20640052 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2010.04.006 |
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