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Pd(0)/InI-Mediated Allylic Additions to 4-Acetoxy-2-Azetidinone: New Route to Highly Functionalized Carbocyclic Scaffolds

[Image: see text] Acylnitroso-derived hetero-Diels-Alder cycloadducts are susceptible to C–O bond cleavage with Pd(0) and InI to form allylic indium (III) species. The in situ prepared allylindium compounds readily react at room temperature with Eschenmoser’s salt. Allylation of 4-acetoxy-2-azetidin...

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Detalhes bibliográficos
Main Authors: Cesario, Cara, Miller, Marvin J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2692034/
https://ncbi.nlm.nih.gov/pubmed/19216521
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol9000685
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