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Structural characterizations of an Re(IV) complex [ReCl(4)(OPPh(3))(2)] and of an imino species [ReOCl(2)(PPh(3))(η(2)-OC(6)H(4)-2-CH=NH)] prepared from the reaction of [ReOCl(3)(PPh(3))(2)] with salicylaldoxime
The reaction of [ReOCl(3)(PPh(3))(2)] with salicylaldoxime unexpectedly yields [ReCl(4)(OPPh(3))(2)] (1) and [ReOCl(2)(PPh(3))(η(2)-OC(6)H(4)-2-CH=NH)] (2). The crystal structure of the Re(IV) complex 1 consists of discrete mononuclear units. The Re site is bound to four chlorides and two trans oxyg...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2000
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2901877/ https://ncbi.nlm.nih.gov/pubmed/20628542 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/S0020-1693(00)00145-6 |
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