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The Identity of the Nucleophile Substitution may Influence Metal Interactions with the Cleavage Site of the Minimal Hammerhead Ribozyme

Potential metal interactions with the cleavage site of a minimal hammerhead ribozyme (mHHRz) were probed using (31)P NMR-detected Cd(2+) titration studies of HHRz constructs containing a phosphorothioate (PS) modification at the cleavage site. The mHHRz nucleophile position was replaced by either a...

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Hlavní autoři: Osborne, Edith M., Ward, W. Luke, Ruehle, Max Z., DeRose, Victoria J.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2901799/
https://ncbi.nlm.nih.gov/pubmed/19778032
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi900614v
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