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Enantioselective Synthesis of 3,4-Chromanediones via Asymmetric Rearrangement of 3-Allyloxyflavones

[Image: see text] Asymmetric scandium (III)-catalyzed rearrangement of 3-allyloxyflavones was utilized to prepare chiral, non-racemic 3,4-chromanediones in high yields and enantioselectivities. These synthetic intermediates have been further elaborated to novel heterocyclic frameworks including angu...

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Bibliografiske detaljer
Main Authors: Marié, Jean-Charles, Xiong, Yuan, Min, Geanna K., Yeager, Adam R., Taniguchi, Tohru, Berova, Nina, Schaus, Scott E., Porco, John A.
Format: Artigo
Sprog:Inglês
Udgivet: 2010
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2896495/
https://ncbi.nlm.nih.gov/pubmed/20527786
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo100889c
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