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First Example of Intramolecular [2π+2π] Alkene-Arene Photocyclization in the Chromone Series and its Synthetic Utility1

Diels-Alder adducts of chromones are shown to undergo an intramolecular [2(π)+2(π)] alkene-arene photocyclization, leading to a versatile polycyclic diene, which is capable of dimerization or can be introduced into a high yielding photoprotolytic oxametathetic sequence. This allows for an expeditiou...

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Detalhes bibliográficos
Main Authors: Valiulin, Roman A., Kutateladze, Andrei G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2895673/
https://ncbi.nlm.nih.gov/pubmed/20607148
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2010.05.078
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