Cargando...
Rhodium Phosphine-π-Arene Intermediates in the Hydroamination of Alkenes
A detailed mechanistic study of the intramolecular hydroamination of alkenes with amines catalyzed by rhodium complexes of a biaryldialkylphosphine are reported. The active catalyst is shown to contain the phosphine ligand bound in a κ(1), η(6) form in which the arene is π-bound to rhodium. Addition...
Guardado en:
| Autores principales: | , , , |
|---|---|
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2011
|
| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3075068/ https://ncbi.nlm.nih.gov/pubmed/21309512 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1057949 |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|