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Asymmetric Synthesis of d-ribo-Phytosphingosine from 1-Tetradecyne and (4-Methoxyphenoxy)acetaldehyde
[Image: see text] An asymmetric synthesis of d-ribo-phytosphingosine (1) was achieved by utilizing the ProPhenol-catalyzed alkynylation of aldehyde 8 to afford allylic propargylic alcohol (S)-6 followed by asymmetric epoxidation and opening of propargylic epoxy alcohol anti-5 with NaN(3)/NH(4)Cl. De...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2892910/ https://ncbi.nlm.nih.gov/pubmed/20527744 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo100707d |
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