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Exploring Symmetry-Based Logic for a Synthesis of Palau’amine
[Image: see text] A synthetic approach to palau’amine is described that exploits veiled symmetry in the structure. Bis-alkylidenes i have been prepared and found susceptible to halogenative desymmetrization using t-BuOCl. This oxidation forms the imbedded spirocyclopentane motif observed in the natu...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2888864/ https://ncbi.nlm.nih.gov/pubmed/19603820 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo900755r |
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