Exploring Symmetry-Based Logic for a Synthesis of Palau’amine

[Image: see text] A synthetic approach to palau’amine is described that exploits veiled symmetry in the structure. Bis-alkylidenes i have been prepared and found susceptible to halogenative desymmetrization using t-BuOCl. This oxidation forms the imbedded spirocyclopentane motif observed in the natu...

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Bibliographic Details
Main Authors: Li, Qingyi, Hurley, Paul, Ding, Hui, Roberts, Andrew G., Akella, Radha, Harran, Patrick G.
Format: Artigo
Language:Inglês
Published: 2009
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2888864/
https://ncbi.nlm.nih.gov/pubmed/19603820
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo900755r
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