Near-IR MCD of the Non-Heme Ferrous Active Site in Naphthalene 1,2-Dioxygenase: Correlation to Crystallography and Structural Insight into the Mechanism of Rieske Dioxygenases

Near-IR MCD and variable temperature, variable field (VTVH) MCD have been applied to Naphthalene 1,2-dioxygenase (NDO) to describe the coordination geometry and electronic structure of the mononuclear non-heme ferrous catalytic site in the resting and substrate-bound forms with the Rieske 2Fe2S clus...

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Bibliographic Details
Main Authors: Ohta, Takehiro, Chakrabarty, Sarmistha, Lipscomb, John D., Solomon, Edward I.
Format: Artigo
Language:Inglês
Published: 2008
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2886598/
https://ncbi.nlm.nih.gov/pubmed/18189388
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja074769o
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