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Catalytic Enantioselective Total Syntheses of Bakkenolides I, J and S: Application of a Carbene-Catalyzed Desymmetrization
[Image: see text] A general strategy for the catalytic asymmetric syntheses of the bakkenolides is reported. The key bond-forming step involves an N-heterocyclic carbene catalyzed desymmetrization of a 1,3-diketone to form three new bonds in one step with excellent enantio– and diastereoselectivity....
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2884059/ https://ncbi.nlm.nih.gov/pubmed/20469924 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100938j |
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