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Examination of the Mechanism of Rh(2)(II)-Catalyzed Carbazole Formation Using Intramolecular Competition Experiments
The use of a rhodium(II) carboxylate catalyst enables the mild and stereoselective formation of carbazoles from biaryl azides. Intramolecular competition experiments of triaryl azides suggested the source of the selectivity. A primary intramolecular kinetic isotope effect was not observed and correl...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2009
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2883892/ https://ncbi.nlm.nih.gov/pubmed/19663433 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo901224k |
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