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Rh(2)(II)-Catalyzed Nitro-group Migration Reactions: Selective Synthesis of 3-Nitroindoles from β-Nitro Styryl Azides
Rhodium carboxylate complexes (1 mol %) catalyze the migration of electron withdrawing groups to selectively produce 3-substituted indoles from β-substituted styryl azides. The relative order of migratorial aptitude for this transformation is ester ≪ amide < H < sulfonyl < benzoyl ≪ nitro....
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3082431/ https://ncbi.nlm.nih.gov/pubmed/21401042 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja111060q |
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