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Dynamics and the Failure of Transition State Theory in Alkene Hydroboration
[Image: see text] Transition state theory fails to accurately predict the selectivity in an example where it is ubiquitously invoked, hydroboration. The hydroboration of terminal alkenes with BH(3) is moderately regioselective, affording an 88:12 - 90:10 ratio of anti-Markovnikov:Markovnikov adducts...
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| Main Authors: | , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2009
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2880641/ https://ncbi.nlm.nih.gov/pubmed/19215077 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja807666d |
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