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Methoxypyridines in the Synthesis of Lycopodium Alkaloids: Total Synthesis of (±)–Lycoposerramine R

[Image: see text] A methoxypyridine serves as a masked pyridone in a concise synthesis of the Lycopodium alkaloid lycoposerramine R, which has been prepared for the first time. The key step of the synthesis is the use of an Eschenmoser Claisen rearrangement to forge a key quaternary carbon center.

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書誌詳細
主要な著者: Bisai, Vishnumaya, Sarpong, Richmond
フォーマット: Artigo
言語:Inglês
出版事項: 2010
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2878394/
https://ncbi.nlm.nih.gov/pubmed/20441180
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100823t
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