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Stereoselective Additions of Thiyl Radicals to Terminal Ynamides
[Image: see text] Two complementary sets of conditions for radical additions of thiols to terminal ynamides are described. The use of 1 equiv of thiol affords the cis-β-thioenamide adducts in rapid fashion (10 min) and good dr, whereas employing excess thiol and longer reaction times favors the tran...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2878391/ https://ncbi.nlm.nih.gov/pubmed/20438051 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol1008679 |
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