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Gas-phase water-mediated equilibrium between methylglyoxal and its geminal diol
In aqueous solution, aldehydes, and to a lesser extent ketones, hydrate to form geminal diols. We investigate the hydration of methylglyoxal (MG) in the gas phase, a process not previously considered to occur in water-restricted environments. In this study, we spectroscopically identified methylglyo...
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| Autores principales: | , , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
National Academy of Sciences
2010
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2872392/ https://ncbi.nlm.nih.gov/pubmed/20142510 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0912121107 |
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