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Gas-phase water-mediated equilibrium between methylglyoxal and its geminal diol

In aqueous solution, aldehydes, and to a lesser extent ketones, hydrate to form geminal diols. We investigate the hydration of methylglyoxal (MG) in the gas phase, a process not previously considered to occur in water-restricted environments. In this study, we spectroscopically identified methylglyo...

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Detalhes bibliográficos
Main Authors: Axson, Jessica L., Takahashi, Kaito, De Haan, David O., Vaida, Veronica
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2872392/
https://ncbi.nlm.nih.gov/pubmed/20142510
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0912121107
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