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Torquoselective Ring-Closures of Chiral Amido-Trienes Derived from Allenamides. A Tandem Allene Isomerization–Pericyclic Ring-Closure–Intramolecular Diels-Alder Cycloaddition
[Image: see text] A new torquoselective ring-closure of chiral amide-substituted 1,3,5-hexatrienes and its application in tandem with [4 + 2] cycloaddition are described. The trienes were derived via either a 1,3-H or 1,3-H–1,7-H shift of α-substituted allenamides, and the entire sequence through th...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2010
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2862010/ https://ncbi.nlm.nih.gov/pubmed/20170149 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol902821w |
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