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An efficient and practical entry to 2-amido-dienes and 3-amido-trienes from allenamides through stereoselective 1,3-hydrogen shifts

Preparations of de novo acyclic 2-amido-dienes and 3-amido-trienes through 1,3-hydrogen shifts from allenamides are described. These 1,3-hydrogen shifts could be achieved thermally or they could be promoted by the use of Brønsted acids. Under either condition, these processes are highly regioselecti...

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Main Authors: Hayashi, Ryuji, Feltenberger, John B, Lohse, Andrew G, Walton, Mary C, Hsung, Richard P
Formáid: Artigo
Teanga:Inglês
Foilsithe: Beilstein-Institut 2011
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3079123/
https://ncbi.nlm.nih.gov/pubmed/21512601
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.53
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