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Iridium Catalyzed C-C Coupling via Transfer Hydrogenation: Carbonyl Addition from the Alcohol or Aldehyde Oxidation Level Employing 1,3-Cyclohexadiene

[Image: see text] Under hydrogen auto-transfer conditions employing a catalyst derived from [Ir(cod)Cl](2) and BIPHEP, 1,3-cyclohexadiene (CHD) couples to benzylic alcohols 1a-9a to furnish carbonyl addition products 1c-9c, which appear as single diastereomers with variable quantities of regioisomer...

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Main Authors: Bower, John F., Patman, Ryan L., Krische, Michael J.
格式: Artigo
語言:Inglês
出版: 2008
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2860772/
https://ncbi.nlm.nih.gov/pubmed/18254642
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol800159w
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