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Enantioselective, Organocatalytic Reduction of Ketones using Bifunctional Thiourea-Amine Catalysts
[Image: see text] Prochiral ketones are reduced to enantioenriched, secondary alcohols using catecholborane and a family of air-stable, bifunctional thiourea-amine organocatalysts. Asymmetric induction is proposed to arise from the in situ complexation between the borane and chiral thiourea-amine or...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2860298/ https://ncbi.nlm.nih.gov/pubmed/20334398 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100365c |
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