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Model Studies of the Histidine-Tyrosine Cross-Link in Cytochrome c Oxidase Reveal the Flexible Substituent Effect of the Imidazole Moiety
[Image: see text] Experimental and theoretical studies were carried out to interrogate the effect of an imidazole substituent in each of the ortho, meta, and para positions on the pK(a), E°, and O–H BDE of phenol. The results reveal that imidazole substitution lowers the pK(a) of phenol and increase...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2005
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2857394/ https://ncbi.nlm.nih.gov/pubmed/15957934 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol050916g |
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