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An Alkoxide Anion Triggered tert-Butyloxycarbonyl Group Migration. Mechanism and Application
We report a fast N→O tert-butyloxycarbonyl (Boc) migration of the imide (3R,4R)-tert-butyl 3-((6-(bis(tert-butoxycarbonyl)amino)-4-methylpyridin-2-yl)methyl)-4-hydroxypyrrolidine-1-carboxylate (2) via a base-generated alkoxide. The mechanism of the migration is intramolecular, involving an unusual n...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2856655/ https://ncbi.nlm.nih.gov/pubmed/20414457 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2010.03.009 |
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