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New Light on NO Bonding in Fe(III) Heme Proteins from Resonance Raman Spectroscopy and DFT Modeling

Visible and ultraviolet resonance Raman (RR) spectra are reported for Fe(III)(NO) adducts of myoglobin variants with altered polarity in the distal heme pockets. The stretching frequencies of the Fe(III)–NO and N–O bonds, ν(FeN) and ν(NO), are negatively correlated, consistent with backbonding. Howe...

詳細記述

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書誌詳細
主要な著者: Soldatova, Alexandra V., Ibrahim, Mohammed, Olson, John S., Czernuszewicz, Roman S., Spiro, Thomas G.
フォーマット: Artigo
言語:Inglês
出版事項: 2010
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2853766/
https://ncbi.nlm.nih.gov/pubmed/20218710
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja906233m
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