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Probing intermediates in the activation cycle of [NiFe] hydrogenase by infrared spectroscopy: the Ni-SI(r) state and its light sensitivity
The [NiFe] hydrogenase from the sulphate-reducing bacterium Desulfovibrio vulgaris Miyazaki F is reversibly inhibited in the presence of molecular oxygen. A key intermediate in the reactivation process, Ni-SI(r), provides the link between fully oxidized (Ni-A, Ni-B) and active (Ni-SI(a), Ni-C and Ni...
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| Autori principali: | , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Springer-Verlag
2009
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2847147/ https://ncbi.nlm.nih.gov/pubmed/19626348 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-009-0566-9 |
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