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Just a Proton: Distinguishing the Two Electronic States of Five-Coordinate High-Spin Iron(II) Porphyrinates with Imidazole/ate Coordination

We report detailed studies on two S = 2 electronic states of high-spin iron(II) porphyrinates. These two states are exemplified by the five-coordinate derivatives with either neutral imidazole or anionic imidazolate as the axial ligand. The application of several physical methods all demonstrate dis...

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Bibliografiska uppgifter
Huvudupphovsmän: Hu, Chuanjiang, Sulok, Corinne D., Paulat, Florian, Lehnert, Nicolai, Twigg, Anna I., Hendrich, Michael P., Schulz, Charles E., Scheidt, W. Robert
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2010
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Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC2846462/
https://ncbi.nlm.nih.gov/pubmed/20192189
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja907584x
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