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Fluctuation enhanced electrochemical reaction rates at the nanoscale
The electrode potential constitutes a dynamical variable whenever an electrode is resistively coupled to the electric circuit. We show that at the nanoscale, the discreteness and stochasticity of an electron transfer event causes fluctuations of the electrode potential that render all elementary ele...
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| Hlavní autoři: | , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
National Academy of Sciences
2010
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| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2842024/ https://ncbi.nlm.nih.gov/pubmed/20176966 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0909240107 |
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