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Fluctuation-enhanced electric conductivity in electrolyte solutions

We analyze the effects of an externally applied electric field on thermal fluctuations for a binary electrolyte fluid. We show that the fluctuating Poisson–Nernst–Planck (PNP) equations for charged multispecies diffusion coupled with the fluctuating fluid momentum equation result in enhanced charge...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Péraud, Jean-Philippe, Nonaka, Andrew J., Bell, John B., Donev, Aleksandar, Garcia, Alejandro L.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2017
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5642729/
https://ncbi.nlm.nih.gov/pubmed/28973890
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1714464114
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