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Oxysterols from Free Radical Chain Oxidation of 7-Dehydrocholesterol: Product and Mechanistic Studies

Free radical chain oxidation of highly oxidizable 7-dehydrocholesterol (7-DHC) initiated by 2,2′-azobis(4-methoxy-2,4-dimethylvaleronitrile) was carried out at 37°C in benzene for 24 hours. Fifteen oxysterols derived from 7-DHC were isolated and characterized with 1D- and 2D-NMR spectroscopy and mas...

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Bibliografske podrobnosti
Main Authors: Xu, Libin, Korade, Zeljka, Porter, Ned A.
Format: Artigo
Jezik:Inglês
Izdano: 2010
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2839323/
https://ncbi.nlm.nih.gov/pubmed/20121089
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9080265
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