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Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes
[Image: see text] An efficient Cu-catalyzed protocol for enantioselective addition of a dimethylphenylsilanyl group to a wide range of cyclic and acyclic unsaturated ketones, esters, acrylonitriles and α,β,γ,δ-dienones is disclosed. Reactions are performed in the presence of 1–2 mol % of commerciall...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2836128/ https://ncbi.nlm.nih.gov/pubmed/20148561 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja910989n |
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