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Rate Acceleration by Stereopopulation Control: Models for Enzyme Action

As a result of alkyl substitution in both aromatic ring and side chain, the rate constant for acid-catalyzed lactonization of hydrocoumaric acid is increased by factors as high as 10(11) and, in comparison with the bimolecular esterification of phenol and acetic acid, by almost 10(16). In the most f...

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Detalhes bibliográficos
Main Authors: Milstien, Sheldon, Cohen, Louis A.
Formato: Artigo
Idioma:Inglês
Publicado em: 1970
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC283329/
https://ncbi.nlm.nih.gov/pubmed/5274444
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