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Role of Heterogeneity of the Solvation Site in Electronic Spectra in Solution

The emission spectra of polar aromatic molecules in rigid, polar solution are shown to depend on the exciting wavelength. Occurrence of the phenomenon depends on both the excited-state lifetime of the chromophore and the degree of rigidity of the medium. The results are interpreted in terms of a mod...

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Pubblicato in:Proc Natl Acad Sci U S A
Autori principali: Galley, William C., Purkey, Robert M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 1970
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Accesso online:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC283325/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16591878/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.67.3.1116
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