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Comparison of rotational barriers of related diphenylmethyl anions and cations studied by (13)C NMR spectroscopy: Mechanistic and structural considerations

The rotational barriers of diphenylmethyl anions and cations were measured through their temperature-dependent (13)C NMR spectra. The ground state structures were found to possess a symmetrical propeller nature. The mechanism for phenyl rotation involves a nonsynchronous process, in which in the tra...

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Autores principales: Olah, George A., Watkins, Michael I.
Formato: Artigo
Lenguaje:Inglês
Publicado: 1980
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC348348/
https://ncbi.nlm.nih.gov/pubmed/16592774
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