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Is the Breakdown of the Born-Oppenheimer Approximation Responsible for Internal Conversion in Large Molecules?

Vibronic radiationless transitions in large polyatomic molecules can be thought of as a process whereby the molecule, initially prepared in a discrete quasistationary state, makes a transition to an adjoining vibronic continuum belonging to a lower electronic state of the same multiplicity. In many...

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Bibliographic Details
Main Authors: Burland, D. M., Robinson, G. W.
Format: Artigo
Language:Inglês
Published: 1970
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC283037/
https://ncbi.nlm.nih.gov/pubmed/16591837
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