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Iridium-Catalyzed (Z)-Trialkylsilylation of Terminal Olefins

[Image: see text] A complex of commercial [Ir(OMe)(cod)](2) and 4,4-di-tert-butyl-2,2-bipyridine (dtbpy) catalyzes the Z-selective, dehydrative silylation of terminal alkenes, but not 1,2-disubstituted alkenes, with triethylsilane or benzyldimethylsilane in THF at 40 °C. Yields and Z-stereoselectivi...

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Bibliographic Details
Main Authors: Lu, Biao, Falck, J. R.
Format: Artigo
Language:Inglês
Published: 2010
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2830331/
https://ncbi.nlm.nih.gov/pubmed/20136153
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo902678p
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