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Entering the leinamycin rearrangement via 2-(trimethylsilyl)ethyl sulfoxides
Attack of cellular thiols on the antitumor natural product leinamycin is believed to generate a sulfenate intermediate that undergoes subsequent rearrangement to a DNA-alkylating episulfonium ion. Here, 2-(trimethylsilyl)ethyl sulfoxides were employed in a fluoride-triggered generation of sulfenate...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2812901/ https://ncbi.nlm.nih.gov/pubmed/17571189 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b701179b |
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