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Mechanistic Duality in Palladium-Catalyzed, Cross-Coupling Reactions of Aryldimethylsilanolates. The Intermediacy of an 8-Si-4 Arylpalladium(II) Silanolate
[Image: see text] The mechanism of palladium-catalyzed cross-coupling reactions of potassium aryl(dimethyl)silanolate K(+)1(−) has been investigated. Under catalysis by (t-Bu(3)P)(2)Pd the coupling with 2-bromofluorobenzene (2) displays the following rate equation: rate = k(obs)[R(3)SiOK](0)[ArylBr]...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2010
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2812642/ https://ncbi.nlm.nih.gov/pubmed/20058920 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja907049y |
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