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Enantioselective organocatalytic α-sulfenylation of substituted diketopiperazines

The asymmetric organocatalytic α-sulfenylation of substituted piperazine-2,5-diones is reported, with cinchona alkaloids as chiral Lewis bases and electrophilic sulfur transfer reagents. Catalyst loadings, the type of sulfur transfer reagent, temperature and solvent were investigated in order to opt...

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Main Authors: Polaske, Nathan W., Dubey, Ramin, Nichol, Gary S., Olenyuk, Bogdan
格式: Artigo
語言:Inglês
出版: 2009
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2811878/
https://ncbi.nlm.nih.gov/pubmed/20161615
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetasy.2009.10.037
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