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Enantioselective organocatalytic α-sulfenylation of substituted diketopiperazines

The asymmetric organocatalytic α-sulfenylation of substituted piperazine-2,5-diones is reported, with cinchona alkaloids as chiral Lewis bases and electrophilic sulfur transfer reagents. Catalyst loadings, the type of sulfur transfer reagent, temperature and solvent were investigated in order to opt...

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Detalhes bibliográficos
Main Authors: Polaske, Nathan W., Dubey, Ramin, Nichol, Gary S., Olenyuk, Bogdan
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2811878/
https://ncbi.nlm.nih.gov/pubmed/20161615
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetasy.2009.10.037
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