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Recrossing and Dynamic Matching Effects on Selectivity in a Diels-Alder Reaction
The products from the hetero-Diels-Alder reaction of acrolein with methyl vinyl ketone arise from a single transition state and trajectory studies accurately predict the selectivity. In an extension of the dynamic matching idea of Carpenter, the product formed is determined by the direction of motio...
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| Autori principali: | , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2009
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2810121/ https://ncbi.nlm.nih.gov/pubmed/19876990 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200903293 |
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