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Recrossing and Dynamic Matching Effects on Selectivity in a Diels-Alder Reaction

The products from the hetero-Diels-Alder reaction of acrolein with methyl vinyl ketone arise from a single transition state and trajectory studies accurately predict the selectivity. In an extension of the dynamic matching idea of Carpenter, the product formed is determined by the direction of motio...

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Detalhes bibliográficos
Main Authors: Wang, Zhihong, Hirschi, Jennifer S., Singleton, Daniel A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2810121/
https://ncbi.nlm.nih.gov/pubmed/19876990
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200903293
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