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H(+), CH(3)(+) and R(3)Si(+) Carborane Reagents: When Triflates Fail
For decades, triflic acid, methyl triflate and trialkylsilyl triflate reagents have served synthetic chemistry well as clean, strong electrophilic sources of H(+), CH(3)(+) and R(3)Si(+) respectively. However, a number of weakly basic substrates are unreactive towards these reagents. In addition, tr...
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2010
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| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2808449/ https://ncbi.nlm.nih.gov/pubmed/19736934 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ar900159e |
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