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H(+), CH(3)(+) and R(3)Si(+) Carborane Reagents: When Triflates Fail

For decades, triflic acid, methyl triflate and trialkylsilyl triflate reagents have served synthetic chemistry well as clean, strong electrophilic sources of H(+), CH(3)(+) and R(3)Si(+) respectively. However, a number of weakly basic substrates are unreactive towards these reagents. In addition, tr...

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Hlavní autor: Reed, Christopher A.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2010
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2808449/
https://ncbi.nlm.nih.gov/pubmed/19736934
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ar900159e
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