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Synthesis and biochemical evaluation of des-vinyl secologanin aglycones with alternate stereochemistry

Based on the X-ray structure of the enzyme strictosidine synthase, the glucose moiety of the seco-iridoid glucoside, secologanin, appears to be the key for orienting the substrate. We hypothesized that removing the glucose moiety would allow alternate stereoisomers of secologanin to be turned over....

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Bernhardt, Peter, O’Connor, Sarah E.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2009
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2799893/
https://ncbi.nlm.nih.gov/pubmed/20161519
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2009.09.171
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