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Synthesis and biochemical evaluation of des-vinyl secologanin aglycones with alternate stereochemistry

Based on the X-ray structure of the enzyme strictosidine synthase, the glucose moiety of the seco-iridoid glucoside, secologanin, appears to be the key for orienting the substrate. We hypothesized that removing the glucose moiety would allow alternate stereoisomers of secologanin to be turned over....

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Bernhardt, Peter, O’Connor, Sarah E.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2009
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC2799893/
https://ncbi.nlm.nih.gov/pubmed/20161519
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2009.09.171
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