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Synthesis and biochemical evaluation of des-vinyl secologanin aglycones with alternate stereochemistry
Based on the X-ray structure of the enzyme strictosidine synthase, the glucose moiety of the seco-iridoid glucoside, secologanin, appears to be the key for orienting the substrate. We hypothesized that removing the glucose moiety would allow alternate stereoisomers of secologanin to be turned over....
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2009
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2799893/ https://ncbi.nlm.nih.gov/pubmed/20161519 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2009.09.171 |
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