Asymmetric Intermolecular Boron Heck-Type Reactions via Oxidative Palladium(II) Catalysis Using Chiral Tridentate NHC-Amidate-Alkoxide Ligands

Chiral dimeric tridentate NHC-amidate-alkoxide palladium(II) complexes, 3a and 3b, effected oxidative boron Heck-type reactions of aryl boronic acids with both acyclic and cyclic alkenes at room temperature to afford the corresponding coupling products with high enantioselectivities. The high degree...

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Main Authors: Yoo, Kyung Soo, O’Neill, Justin, Sakaguchi, Satoshi, Giles, Richard, Lee, Joo Ho, Jung, Kyung Woon
格式: Artigo
語言:Inglês
出版: 2010
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2798920/
https://ncbi.nlm.nih.gov/pubmed/19954185
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo901977n
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