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Direct Observation of a Photo-Induced Non-Stabilized Nitrile Imine Structure in the Solid State
We report the direct observation of a bent geometry for a non-stabilized nitrile imine in a metal-coordination crystal. The photoinduced tetrazole ring rupture to release N(2) appears to depend on the size of voids around the N(3)-N(4) bond in the crystal lattice. We further observed the selective f...
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| Auteurs principaux: | , , , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2009
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2797338/ https://ncbi.nlm.nih.gov/pubmed/19928921 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9094523 |
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