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Electron tunneling through sensitizer wires bound to proteins

We report a quantitative theoretical analysis of long-range electron transfer through sensitizer wires bound in the active-site channel of cytochrome P450cam. Each sensitizer wire consists of a substrate group with high binding affinity for the enzyme active site connected to a ruthenium-diimine thr...

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Autors principals: Hartings, Matthew R., Kurnikov, Igor V., Dunn, Alexander R., Winkler, Jay R., Gray, Harry B., Ratner, Mark A.
Format: Artigo
Idioma:Inglês
Publicat: 2010
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2797321/
https://ncbi.nlm.nih.gov/pubmed/20161508
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ccr.2009.08.008
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