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A kinetic and thermodynamic understanding of O(2) tolerance in [NiFe]-hydrogenases

In biology, rapid oxidation and evolution of H(2) is catalyzed by metalloenzymes known as hydrogenases. These enzymes have unusual active sites, consisting of iron complexed by carbonyl, cyanide, and thiolate ligands, often together with nickel, and are typically inhibited or irreversibly damaged by...

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書誌詳細
主要な著者: Cracknell, James A., Wait, Annemarie F., Lenz, Oliver, Friedrich, Bärbel, Armstrong, Fraser A.
フォーマット: Artigo
言語:Inglês
出版事項: National Academy of Sciences 2009
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2791605/
https://ncbi.nlm.nih.gov/pubmed/19934053
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0905959106
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