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A kinetic and thermodynamic understanding of O(2) tolerance in [NiFe]-hydrogenases
In biology, rapid oxidation and evolution of H(2) is catalyzed by metalloenzymes known as hydrogenases. These enzymes have unusual active sites, consisting of iron complexed by carbonyl, cyanide, and thiolate ligands, often together with nickel, and are typically inhibited or irreversibly damaged by...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2791605/ https://ncbi.nlm.nih.gov/pubmed/19934053 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0905959106 |
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